Thermoelectric Effects Challenge Understanding of Superconductivity in Iron Selenide

Monday 24 March 2025


Scientists have made a fascinating discovery in the field of superconductivity, which has major implications for our understanding of this phenomenon. Researchers at Japan’s National Institute for Materials Science and other institutions have been studying a type of material called iron selenide (FeSe), which is known to exhibit superconducting properties.


Superconductors are materials that can conduct electricity with zero resistance, meaning they can carry electrical current without losing any energy. This property makes them incredibly useful for applications such as high-speed transportation and advanced medical equipment.


The scientists were intrigued by FeSe’s unique behavior because it doesn’t require the application of a magnetic field to achieve superconductivity. Most other superconducting materials need an external magnetic field to break time-reversal symmetry, which is essential for achieving zero resistance.


In their study, the researchers used advanced techniques such as low-frequency ac measurements and dc current-voltage measurements to investigate FeSe’s properties. They found that the material exhibits a second-harmonic resistance, which is a measure of how much electricity flows through it in response to an external magnetic field.


The team was surprised to discover that this second-harmonic resistance was not due to genuine nonreciprocal transport, but rather caused by joule heating at current contacts. Joule heating occurs when electrical current flows through a material and generates heat, which can affect its properties.


Further analysis revealed that the thermoelectric effect was responsible for the observed second-harmonic resistance. The thermoelectric effect is a phenomenon where an electric current generates a temperature gradient in a material, and vice versa.


The researchers used advanced computer simulations to model their findings and found that the large thermoelectric coefficients in FeSe were responsible for the observed effects. These coefficients determine how much electricity flows through a material in response to a temperature gradient.


The significance of this discovery is that it challenges our understanding of superconductivity. It suggests that thermoelectric effects can dominate over genuine nonreciprocal transport in certain materials, making it crucial to consider these effects when designing experiments and interpreting results.


Furthermore, the study highlights the importance of careful measurement techniques and accurate data analysis. The researchers’ findings demonstrate that even seemingly anomalous experimental results can be explained by simple physical mechanisms, such as joule heating and thermoelectric effects.


This research has far-reaching implications for the development of new superconducting materials and devices.


Cite this article: “Thermoelectric Effects Challenge Understanding of Superconductivity in Iron Selenide”, The Science Archive, 2025.


Superconductivity, Iron Selenide, Fese, Magnetic Field, Thermoelectric Effect, Joule Heating, Nonreciprocal Transport, Second-Harmonic Resistance, Computer Simulations, Materials Science


Reference: Taichi Terashima, Shinya Uji, Yuji Matsuda, Takasada Shibauchi, Shigeru Kasahara, “Apparent nonreciprocal transport in FeSe bulk crystals” (2025).


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